Affiliation:
1. Institut für Anorganische Chemie der Universität München
Abstract
Abstract
P-perhalogenated cyclotri(λ3 -phosphazanes) 3 a, b are obtained from the reaction of 1 or 2 with excess PX3 (X = Cl, Br). Under mild reaction conditions 4-7 are found to be intermediates. The existence of a six-membered ring trimer is proven by NMR and mass spectroscopy. No dimer (XPNMe)2 could be detected.
Cited by
16 articles.
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1. Insights into the formation of inorganic heterocycles via cyclocondensation of primary amines with group 15 and 16 halides;Dalton Transactions;2017
2. Reaction of P
4
with in situ Formed
cyclo
‐Triphosphatriazenium Cation [(DmpNP)
3
Cl
2
]
+
(Dmp = 2,6‐Dimethylphenyl);European Journal of Inorganic Chemistry;2015-10-28
3. Experimental and Computational 77Se NMR Investigations of the Cyclic Eight-Membered Selenium Imides 1,3,5,7-Se4(NR)4 (R = Me, tBu) and 1,5-Se6(NMe)2;Inorganic Chemistry;2015-05-01
4. 2,4,6-Trichloro-1,3,5-Triethylcyclophosph(III)Azanes (1,3,5,2,4,6-Triazatriphosphorinanes);Inorganic Syntheses;2007-01-05
5. Triphosph(iii)azanes to diphosph(iii)azanes; a cracking transformation;Dalton Transactions;2005