Affiliation:
1. Institut für Chemie der Universität Regensburg
Abstract
Abstract
The Compound TlFeS2 was synthesized from TlS/Fe/S-mixtures. Crystals are mono-clinic (space group C2/m) with a = 1164.4(6) pm, b = 530.8(3) pm, c = 1050.9(5) pm, β = 144.58° and Z = 4. The structure comprises [FeS2-]∞-chains parallel b, built from edge-shared FeS4-tetrahedra. Relations between TlFeS2 and orthorhombic CsFeS2 are discussed. Tetragonal or monoclinic distorted tetragonal ternary phases occur with composition FexTl2S4 (2.6 < x < 3.6 ).
Cited by
23 articles.
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1. THERMO-FIELD PULA-FRENKEL EFFECT IN TlFeS2 CRYSTALS;«АКТУАЛЬНЫЕ ВОПРОСЫ СОВРЕМЕННОЙ НАУКИ: ТЕОРИЯ, ТЕХНОЛОГИЯ, МЕТОДОЛОГИЯ И ПРАКТИКА». Международная научно-практическая онлайн-конференция, приуроченная к 60-ти летию член-корреспондента Академии наук ЧР, доктора технических наук, профессора Сайд-Альви Юсуповича Муртазаева;2021-06-28
2. Magnetic properties of chain antiferromagnets RbFeSe2, TlFeSe2, and TlFeS2;Bulletin of the Russian Academy of Sciences: Physics;2017-07
3. High-pressure effect on the chain-like crystal structure of the semiconductors TlFeSe2 and TlFeS2;Modern Physics Letters B;2015-03-30
4. Electron diffraction study of the phase formation of Tl-Fe-Se and kinetics of phase transformations of films TlFeSe2;Semiconductors;2014-11
5. Phase transitions and their co-existence in TlGaSe2–TlCrS2(Se2) systems;Bulletin of Materials Science;2013-08