Affiliation:
1. Institut für Anorganische Chemie der Universität Stuttgart, Pfaffenwaldring 55, D-7000 Stuttgart 80
Abstract
The potassium dimethoxi-, -dimethylaminomethoxi- and -bis(dimethylamino)phosphates (1), (2) and (3) were prepared by reaction of KOH and the corresponding phosphoric esterchlorides. 2 reacts with antimony(V) chloride to yield the dimeric tetrachloro- antimony(V) dimethylaminomethoxiphosphate (4). The crystal and molecular structures of 4 and the dimeric tetrachloroantimony(V) dimethoxiphosphate (5) were determined by X-ray analysis. The vibrational and NMR spectra of 1-4 are reported and briefly discussed.
Cited by
11 articles.
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