Affiliation:
1. Institut für Anorganische Chemie der RWTH Aachen, Prof.-Pirlet-Straße 1, D-5100 Aachen
Abstract
Na2S5 has been Synthesized from β-Na2S2 and excess sulfur by a two step reaction. A solid state reaction at 200 °C was carried out, which was then followed by a melting reaction at 500 °C. X-ray investigations on single crystals revealed the structure of the α-modification. The orthorhombic unit cell contains four formula units; the space group is Pnma. The sulfur atoms form unbranched zig-zag-chains S5
2- in cis-conformation
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31 articles.
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