Ba5(GaS4)2: Das erste ortho-Thiogallat(III) / Ba5(GaS4)2: The First ortho-Thiogallate(III)-Reference-Cited by-同舟云学术

Ba5(GaS4)2: Das erste ortho-Thiogallat(III) / Ba5(GaS4)2: The First ortho-Thiogallate(III)

Published:1984-01-01 Issue:1 Volume:39 Page:27-36
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Eisenmann Brigitte¹,Jakowski Mareike¹,Schäfer Herbert¹

Affiliation:

1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt, Hochschulstraße 4. D-6100 Darmstadt

Abstract

The new compound Ba5(GaS4)2 crystallizes in the orthorhombic system (space group: Cmca) with lattice constants a = 2249.4(12) pm, b = 1214.6(8) pm, c = 1188.7(8) pm. In the structure there are isolated GaS4 5- -tetrahedra. According to stoichiometry and structure this compound belongs to the complex salts, and is the first othiogallate(III).

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1984-0106/pdf

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