Affiliation:
1. Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle, D-7400 Tübingen
2. Fachbereich Chemie der Universität Marburg, Hans-Meerwein-Straße, D-3550 Marburg
Abstract
The X-ray structure of PPh3Me[NbOCl4(CH3CN)] at 210 K was solved (space group P1̄, two formula units per unit cell, a = 1173.5(5), b = 1130.1(4), c = 946.8(3) pm, α = 97.70(4), β = 93.57(3), γ = 78.62(3)°, 3688 independent reflexions, R = 0.025).
The material consists of cations [P(C6H5)3CH3]⊕ and anions [NbOCl4(CH3CN)]⊖. The nitrogen atom of the acetonitrile solvate molecule is coordinated to the niobium centre in the trans-position to the oxo ligand; the NbO bond length of 169 pm corresponds to a double bond.
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14 articles.
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