Beiträge zur Untersuchung anorganischer nichtstöchiometrischer Verbindungen, XXIV. Elektronenmikroskopische Untersuchung der Hybridphasen Nb59O147F und Nb65O161F3 / Contributions to the Study of Inorganic Non-Stoichiometric Compounds, XXIV. Electronmicroscopical Investigation of the Hybrid Phases Nb59O147F and Nb65O161F3

Author:

Roß Ronald1,Gruehn Reginald2

Affiliation:

1. Institut für Anorganische und Analytische Chemie der niversität Gießen, Heinrich-Buff-Ring 58, D-6300 Gießen

2. Institut für Anorganische und Analytische Chemie der Universität Gießen, Heinrich-Buff-Ring 58, D-6300 Gießen

Abstract

The hybrid phases Nb59O147F and Nb65O161F3 were prepared at high temperature and investi­gated by high resolution transmission electron microscopy. Both phases have block structures. The sample of the phase Nb59O147F is very well ordered, whereas the phase Nb65O161F3 shows some defects. In a sample of Nb65O161F3 microdomains of a new 2:1 hybrid phase Nb96O238F4 were found. Structural differences of the systems Nb2O5/NbO2F and Nb2O5/WO3 are discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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