Zur Reaktion von Hexamethyldistannoxan und Hexamethyldistannthian mit Phosphor-oxo- bzw. -thio-halogeniden. Schwingungsspektren von (Me2PS)2O und (Me2PS)2S / On the Reactions of Hexamethyldistannoxane and Hexamethyldistannthiane with Phosphorus-oxy and -thio-halides. Vibrational Spectra of (Me2PS)2O and (Me2PS)2S-Reference-Cited by-同舟云学术

Zur Reaktion von Hexamethyldistannoxan und Hexamethyldistannthian mit Phosphor-oxo- bzw. -thio-halogeniden. Schwingungsspektren von (Me2PS)2O und (Me2PS)2S / On the Reactions of Hexamethyldistannoxane and Hexamethyldistannthiane with Phosphorus-oxy and -thio-halides. Vibrational Spectra of (Me2PS)2O and (Me2PS)2S

Published:1984-06-01 Issue:6 Volume:39 Page:783-787
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Shihada Abdel-Fattah¹,Jasim Ihsan A. M.²

Affiliation:

1. Department of Chemistry, College of Science, University of United Arab Emirates, Al-Ain P.O.Box 15551 U.A.E.

2. Department of Chemistry, College of Science, University of Baghdad, Baghdad, Iraq

Abstract

Abstract Me3SnO2PCl2 and (Me2PS)2O are prepared from the reactions of (Me3Sn)2O with POCl3 (1:1) and with Me2PSCl (1:2), respectively. The reactions of (Me3Sn)2S with Me2PSCl and with PSBr3 lead to the formation of (Me2PS)2S and P4S9, respectively. POCl3 reacts with (Me3Sn)2S to give unidentified products as a result of O/S exchange. The i.r. and Raman spectra of the solids (Me2PS)2O and (Me2PS)2S and the Raman spectra of the molten compounds are reported and the frequencies assigned.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1984-0615/pdf

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