Kinetic study of the β → α + γ transformation reaction in a CuZnAl alloy

Author:

De Micco Georgina12,Bohé Ana Ester34,Pasquevich Daniel Miguel13

Affiliation:

1. Comisión Nacional de Energía Atómica (C.N.E.A.), San Carlos de Bariloche , Río Negro , Argentina

2. Instituto Balseiro, Universidad Nacional de Cuyo , Río Negro Argentina

3. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) , Buenos Aires Argentina

4. Centro Regional Universitario Bariloche, Universidad Nacional del Comahue , Córdoba Argentina

Abstract

Abstract In the present work we study the phase transformation reaction of a Cu-20Zn-7Al (wt.%) alloy by isothermal and nonisothermal in situ X-ray diffraction. An effective activation energy for each phase is obtained for the range between 275 and 395 °C. The experimental data are also adjusted with the JMA equations. Finally, we present the TTT (time – temperature – transformation) diagram corresponding to the precipitation of alpha and gamma for the lower temperatures. Below 340 °C, we found for this alloy that the gamma phase precedes the formation of alpha.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

Reference20 articles.

1. G. Petzow, G. Effenberg: Ternary Alloys A Comprehensive Compendium of Evaluated Constitutional Data and Phase Diagrams, Weinhein, Basel, Switzerland/ Cambridge/New York, NY: VCH, Vol. V (1992).

2. M.L. Castro: Phd. Thesis, Universidad Nacional del Centro de la Provincia de Buenos Aires, Argentina(1999).

3. E.-S. Lee, Y.G. Kim: Met. Trans. A 21 (1990) 1681.

4. S. Yon, Y. Han: J. Mater. Sci. 21 (1986) 2711.

5. E.-S. Lee, Y.G. Kim: Scripta Met. et Mater. 24 (1990) 745.

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