Affiliation:
1. Laboratoire de Physico-chimie de la Matière Condensée, Université Montpellier II Montpellier France
2. Now at Institute of Physics, Chinese Academy of Science , Beijing , China
Abstract
Abstract
Available experimental thermodynamic and phase diagram data were critically reviewed. A thermodynamic assessment of the binary In-Se system was performed based on the evaluation of literature. The intermediate compounds taken into account are In4Se3, InSe, In6Se7, In9Se11, In5Se7, and polymorphic In2Se3 (α, β, γ and δ). All these compounds were treated as stoichiometric phases. The liquid phase was described using the association model with the associate species of ‘In2Se3’. A set of thermodynamic parameters was obtained, and the calculated phase diagram is presented.
Subject
Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics
Reference64 articles.
1. H. Hahn, F. Burow: Angew. Chem. 68 (1956) 382.
2. H. Miyazawa, S. Suggaike: J. Phys. Soc. Jpn. 12 (1957) 312.
3. S.A. Semiletov: Kristallografiya 3 (1958) 288.
4. T. Yoshioka: Sci. Reps. Tohoku Univ. First Ser. 44 (1960) 99.
5. G.K. Slavnova, N.P. Luzhnaya, Z.S. Medvedeva: Zhur. Neorg. Khim. 8 (1963) 153.