Preparation and characterization of PEO-based composite gel-polymer electrolytes complexed with lithium trifluoro methane sulfonate-Reference-Cited by-同舟云学术

Preparation and characterization of PEO-based composite gel-polymer electrolytes complexed with lithium trifluoro methane sulfonate

Published:2018-06-01 Issue:2 Volume:36 Page:185-192
ISSN:2083-134X
Container-title:Materials Science-Poland
language:en
Short-container-title:

Author:

Nagajothi A.J.¹,Kannan R.¹,Rajashabala S.²

Affiliation:

1. Department of Physics, University College of Engineering, Anna University, Dindigul -624 622, India

2. School of Physics, Madurai Kamaraj University, Madurai -21, India

Abstract

Abstract Chitosan has been successfully incorporated as a filler in a polyethylene oxide (PEO) and lithium trifluoromethanesulfonate (LiCF3SO3) matrix with a combination of plasticizers, namely 1,3-dioxolane (DIOX) and tetraethylene glycol dimethylether (TEGDME). The composite gel-polymer electrolyte (CGPE) membranes were prepared by solution casting technique in an argon atmosphere. The prepared membranes were subjected to SEM, TG/DTA and FT-IR analyses. A Li/CGPE/Li symmetric cell was assembled and the variation of interfacial resistance was measured as a function of time. The lithium transference number (Li+ t) was measured and the value was calculated as 0.6 which is sufficient for battery applications. The electrochemical stability window of the sample was studied by linear sweep voltammetry and the polymer electrolyte was found to be stable up to 5.2 V.

Publisher

Walter de Gruyter GmbH

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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