Millimeter-Wave Spectrum of Ethyl Acetylene Centrifugal Distortion, Coriolis Interaction and Internal Rotation

Author:

Demaison J.1,Boucher D.1,Burie J.1,Dubrulle A.1

Affiliation:

1. Laboratoire de Spectroscopic Hertzienne associe au CNRS n° 249, Universite de Lille I

Abstract

The rotational spectrum of ethyl acetylene has been investigated between 70 and 320 GHz. A Coriolis interaction has been found between the first excited state of the methyl torsion and the C - C = C in plane deformation. Splittings of transitions in the first excited torsional state show that the barrier hindering internal rotation of the methyl group amounts to 3271 cal/mole.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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