The Influence of Water Addition on Solutions of FeCIi in Isopropanol-Reference-Cited by-同舟云学术

The Influence of Water Addition on Solutions of FeCIi in Isopropanol

Published:1983-06-01 Issue:6 Volume:38 Page:701-702
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Rodriguez F.¹,Moreno M.¹,Fayet J. C.²,Varret F.³

Affiliation:

1. Departamento de Optica y Estructura de la Materia, Facultad de Ciencias, Universidad de Santander. Santander, Spain

2. Laboratoire de Spectroscopic de Solide. ERA 682, Faculte des Sciences du Mans, 72017 Le Mans Cedex, France

3. Laboratoire de Spectrometrie Mössbauer, ERA 682, Faculte des Sciences du Mans, 72017 Le Mans Cedex, France

Abstract

By means of Optical Absorption, EPR and Mössbauer techniques it is demonstrated that the addition of small amounts of water to solutions of FeCl3 in isopropanol enhances the concentration of [FeCl4]- complexes, this addition leading also to the formation of ferric dimers involving two Fe3+-OH- bridges. An explanation of this fact based on the disproportionation of FeCl3 and water hydrolysis is reported

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1983-0614/pdf

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