Affiliation:
1. The Studsvik Science Research Laboratory, S-611 82 Nyköping, Sweden
Abstract
A new matrix, 1,1,1-trifluorotrichloroethane, CF3CCl3, has been employed in radiation chemistry studies to stabilise positive ions. As a test, positive ions of benzene, toluene, orto-, meta- and paraxylene and biphenyl have been generated by y-irradiation of the solutes contained in the CF3CCl3 matrix at 77 K. The ions have been investigated by ESR, and hyperfine couplings have been obtained. The data complement and correct the splitting values obtained previously in the adsorbed state.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
11 articles.
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