Crystal Growth and Crystal Structure of the Metastable Bismuth Orthoborate BiBO3-Reference-Cited by-同舟云学术

Crystal Growth and Crystal Structure of the Metastable Bismuth Orthoborate BiBO3

Published:2004-03-01 Issue:3 Volume:59 Page:256-258
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:
Short-container-title:

Author:

Becker Petra¹,Fröhlich Roland²

Affiliation:

1. 1Institut für Kristallographie der Universität zu Köln, Zülpicher Str. 49 b, D-50674 Köln, Germany

2. 2Organisch-Chemisches Institut, Universität Münster, Corrensstr. 40, D-48149 Münster, Germany

Abstract

Single crystals of bismuth orthoborate, BiBO3, were grown from the melt in the system Li2OBi2O3- B2O3 · BiBO3 is confirmed to adopt at least two different structural modifications. The modification BiBO3(I) (corresponding to PDF Nr. 28-0169) crystallizes with space group P21/c. The structure consists of [Bi2O10] groups that are formed by two edge-sharing distorted [BiO6] octahedra and that are interconnected by sharing common corners (oxygen). The [Bi2O10] groups are further sharing corners with planar [BO3] groups giving a three-dimensional framework

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2004-0302/pdf

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