Affiliation:
1. Institut für Physikalische Chemie; Physikalische Chemie III, Technische Hochschule Darmstadt
2. Institut für Kristallographie und Mineralogie der Universität Frankfurt
Abstract
Abstract
The crystal structure of the high temperature phase of anilinium bromide, C6H5NH3
⊕Br⊖ , was studied by X-ray and neutron diffraction at T = 343 K. The refinement supports disordered positions of the -NH3
⊕ group. A split-atom model is proposed which includes disorder of the benzene ring. The thermal parameters, hydrogen bond distances, and other experimental data (NMR, NQR, inelastic neutron scattering) are in accordance with this model.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
12 articles.
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