Study of Sulfur-Sulfur Nonbonded Interactions in Substituted Diphosphine Disulfides by Gas-Phase UV Photoelectron Spectroscopy-Reference-Cited by-同舟云学术

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Study of Sulfur-Sulfur Nonbonded Interactions in Substituted Diphosphine Disulfides by Gas-Phase UV Photoelectron Spectroscopy

Published:1981-01-01 Issue:1 Volume:36 Page:68-71
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Alagna Lucilla¹,Cauletti Carla¹,Andreocci Marco²,Furlani Claudio²,Hagele Gerhard³

Affiliation:

1. Laboratorio TSECS-CNR, Roma

2. Istituto di Chimica Generale ed Inorganica, Universitä di Roma

3. Institut für Anorganische Chemie der Universität, Düsseldorf

Abstract

Ultraviolet photoelectron spectra (UPS) of tetrasubstituted diphosphine disulfides RR'P(S)- P(S)RR' exhibit peculiar 1:2:1 splitting patterns in the region 7.5-9.5 eV for which a throughbond coupling mechanism between the sulfur lone pairs lying in the PPS planes is proposed. Further bond orbitals are related to bands at higher I. E. in the UP spectra

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1981-0111/pdf

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