Affiliation:
1. Institut für Physikalische Chemie der Universität Düsseldorf, Lehrstuhl I, Düsseldorf
Abstract
The melting enthalpies and entropies of 24 Menshutkin complexes composed of 2SbCl3 and aromatic compounds were measured by calorimetric methods. The relatively large values of these thermodynamic data can be explained under the assumption of a dissociation of the complexes during melting. The association enthalpy can be estimated by separating the melting process into two steps
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
9 articles.
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