Tetramethylcyclopentadienylindium(I) und Tetramethylcyclopentadienylthallium(I): Synthese, Charakterisierung und Röntgenstrukturanalyse / Tetramethylcyclopentadienylindium(I) and Tetramethylcyclopentadienylthallium(I): Synthesis, Characterization and X-Ray Structural Analysis-Reference-Cited by-同舟云学术

Tetramethylcyclopentadienylindium(I) und Tetramethylcyclopentadienylthallium(I): Synthese, Charakterisierung und Röntgenstrukturanalyse / Tetramethylcyclopentadienylindium(I) and Tetramethylcyclopentadienylthallium(I): Synthesis, Characterization and X-Ray Structural Analysis

Published:1992-09-01 Issue:9 Volume:47 Page:1241-1248
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Schumann Herbert¹,Kucht Homa¹,Kucht Andreas¹,Görlitz Frank H.¹,Dietrich Andreas¹

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, Straße des 17. Juni 135, D-W-1000 Berlin 12

Abstract

Tetramethylcyclopentadienyllithium was reacted with InCl to form [C5HMe4]In (1). [C5HMeJTl (2) was prepared from tetramethylcyclopentadiene and T1OC2H5. The 1H and 13C NMR spectra of the new compounds as well as the X-ray crystal structures of the polymeric metallocenes 1 and 2 are reported and discussed in relation to the structures of other cyclopentadienylindium(I) and -thallium(I) compounds.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1992-0905/pdf

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