A comparative study of polyelectrolyte induced metachromasy

Abstract

AbstractThe interaction of two cationic dyes, namely crystal violet (CV), with anionic polyelectrolytes, namely sodium carrageenate (NaCar) and sodium heparinate (NaHep), has been investigated by spectrophotometric method. The polymers induced metachromasy in the dye resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between crystal violet and sodium carrageenate was found to be greater than that formed between crystal violet and sodium heparinate. This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes. The interaction parameters revealed that binding between crystal violet and sodium carrageenate was mainly due to electrostatic interaction while that between crystal violet and sodium heparinate is found to involve both electrostatic and hydrophobic forces.