Analysis of heat capacity and Mössbauer data for LuZnSn2 compound

Author:

Łątka Kazimierz1,Przewoźnik Janusz2,Żukrowski Jan3,Verbovytskyy Yuriy4,Gonçalves Antonio Pereira5

Affiliation:

1. M. Smoluchowski Institute of Physics, Jagiellonian University, 11 Prof. S. Łojasiewicza Str., 30-348 Kraków, Poland, Tel.: +48 12 663 5668, Fax: +48 12 633 7086

2. Department of Solid State Physics, Faculty of Physics and Applied Computer Science, AGH – University of Science and Technology, 30 A. Mickiewicza Ave., 30-059 Kraków, Poland

3. Academic Centre for Materials and Nanotechnology and Department of Solid State Physics, Faculty of Physics and Applied Computer Science, AGH – University of Science and Technology, 30 A. Mickiewicza Ave., 30-059 Kraków, Poland

4. Department of Hydrogen Technologies and Hydride Materials Science, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova Str., 79-060 Lviv, Ukraine

5. Campus Tecnológico e Nuclear, Instituto Superior Técnico/CFMC, Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela LRS, Portugal

Abstract

Abstract New analysis of heat capacity data is presented for LuZnSn2 compound that takes into account anharmonic effects together with the existence of Einstein modes. 119mSn Mössbauer spectroscopy was used to monitor the hyperfine parameters at the two crystallographically inequivalent Sn sites in the studied compound. The problem of non-unique mathematical resonance spectrum description and the problem how to choose physically meaningful set of hyperfine parameters will be thoroughly discussed. Measured quadrupole interaction constants by 119mSn Mössbauer spectroscopy give estimations for Vzz component of electric field gradient tensor at both Sn sites in LuZnSn2.

Publisher

Walter de Gruyter GmbH

Subject

Waste Management and Disposal,Condensed Matter Physics,Safety, Risk, Reliability and Quality,Instrumentation,Nuclear Energy and Engineering,Nuclear and High Energy Physics

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