Macrocyclic tetrakis-phosphines and their copper(I) complexes-Reference-Cited by-同舟云学术

Macrocyclic tetrakis-phosphines and their copper(I) complexes

Published:2017-03-01 Issue:3 Volume:89 Page:331-339
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
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Author:

Musina Elvira I.¹,Wittmann Tatiana I.¹,Dobrynin Alexey B.¹,Lönnecke Peter²,Hey-Hawkins Evamarie²,Karasik Andrey A.¹,Sinyashin Oleg G.¹

Affiliation:

1. 1A.E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Arbuzov-str. 8, 420088 Kazan, Russia

2. 2Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Leipzig University, Johannisallee 29, 04103 Leipzig, Germany

Abstract

AbstractA series of mono-, di- and tetranuclear copper(I) complexes with macrocyclic 14-, 16-, 18- and 20-membered tetrakis-phosphine ligands (P4N2) was obtained and fully characterized including single crystal X-ray diffraction. The 14-membered P4N2 macrocycles form very stable cationic mononuclear tetraphospha-coordinated copper(I) complexes, whereas their higher 16-, 18- and 20-membered homologues give neutral dinuclear [Cu2I2L] complexes under the same conditions. An unusual tetranuclear complex with two three- and two four-coordinated copper(I) atoms was obtained from 16-PMes4NCH2CH2Py-22 and copper(I) iodide. This is the first example of N-coordination of cyclic aminomethylphosphines towards “soft” copper(I).

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/pdf

Reference68 articles.

1. Azamacrocyclic Systems with Different Supramolecular Functions

2. Templation and encapsulation in supramolecular chemistry

3. Sexidentate phosphorus-containing macrocyclic ligands. Synthesis of 1,10-dipropyl-4,7,13,16-tetraphenyl-1,10-diaza-4,7,13,16-tetraphospha-cyclooctadecane

4. Program for empirical ray absorption correction;Sheldrick,2004

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