Synthesen mit nitrilen XXXI / Syntheses with nitriles, XXXI

Author:

Junek H.1,Aigner H.1

Affiliation:

1. Institut für Organische Chemie der Universität Graz

Abstract

Tetracyanoethylene was added to dihydroresorcine and dimethyldihydroresorcine which yielded 2-amino-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3,4,4-tricarbonitriles by cyclization. Dimethyl-dihydro-resorcine-monoimine together with tetracyanoethylene eliminated HCN and resulted in a 7,7-dimethyl-tetrahydro-quinoline derivative. The structures were proved by alkaline degradation and by IR- and NMR-spectroscopy

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 14 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Synthesis, Structure, Chemical Reactivity, and Practical Significance of 2-Amino-4H-pyrans;Advances in Heterocyclic Chemistry;2011

2. Synthesis of the Quinoline Ring System;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

3. Carbocyclic Annelated Pyridines;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

4. Synthetic and Natural Sources of the Pyridine Ring;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

5. Interaction of tetracyanoethylene with α,β-unsaturated aldehydes. Synthesis of 2,4-dialkyl-7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles;Tetrahedron Letters;2007-04

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