Rotational Spectra of Fluorodiacetylene and Fluorotriacetylene Produced by Electrical Discharge

Author:

Dreizler Helmut1,Mata Santiago2,Lesarri Alberto2,López Juan C.2,Blanco Susana2,Alonso José L.2

Affiliation:

1. 1Institut für Physikalische Chemie der Christian-Albrechts-Universität Kiel, Olshausenstr. 40, D-24098 Kiel

2. 2Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid, 47005 Valladolid, Spain

Abstract

The rotational spectra of discharge produced 13C isotopomers of fluorodiacetylene were recorded with high sensitivity to improve the centrifugal distortion analysis. Stimulated by the sensitivity attained by the spectrometer the investigation was extended to detect the hitherto unknown fluorotriacetylene. The spectrum of a linear molecule was found, which with high probability belongs to fluorotriacetylene

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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