Affiliation:
1. Institut für Physikalische Chemie und Elektrochemie der Universität Karlsruhe
Abstract
Abstract
The decomposition of di-tertiary-butyl-peroxide dissolved in n-heptane has been measured ir-spectroscopically up to pressures of 2300 bar at temperatures between 140 °C and 200 °C. The reaction follows a first order rate law with an activation energy Ea = 151.4 ± 1.6 kJ mol-1 and an activation volume ΔV ǂ = 10.1 ± 1.1 cm3 mol-1. The effectivity of the peroxide decomposition is discussed.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
36 articles.
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