Self-Association of Cholesterol in Carbon Tetrachloride-Reference-Cited by-同舟云学术

Self-Association of Cholesterol in Carbon Tetrachloride

Published:1979-03-01 Issue:3 Volume:34 Page:369-374
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Kunst M.¹,Duijn D. van¹,Bordewijk P.¹

Affiliation:

1. Gorlaeus Laboratories, Department of Physical Chemistry, University of Leiden, P. 0. B. 9502, 2300 RA Leiden, The Netherlands

Abstract

Abstract Analysis of infrared hydroxyl multimer absorbances of dilute solutions of cholesterol in carbon tetrachloride as a function of the monomer absorbance strongly favours the interpretation of the association of this alcohol with a monomer-dimer-tetramer model up to a molar fraction of 0.012. This model also explains very well the concentration dependence of the apparent dipole moment. Equilibrium constants and dielectric parameters have been determined. Suggestions about the structure of the various associates are made.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1979-0313/pdf

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1. Hydrogen bonding of 5α-cholestanol in carbon tetrachloride;Recueil des Travaux Chimiques des Pays-Bas;2010-09-02

2. Cholesterol complexes with some proton acceptors in benzene and toluene solutions;Monatshefte für Chemie - Chemical Monthly;2009-03-12

3. Cholesterol complexes with tri-n-butylphosphate, tri-n-octylamine and cyclohexanone in chlorinated hydrocarbon solvents;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2007-04

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