Nuclear Magnetic Resonance in Solid Zinc

Author:

Herberg H.1,Abart J.1,Voitländer J.1

Affiliation:

1. Institut für Physikalische Chemie der Universität München

Abstract

Abstract The nuclear magnetic resonance of 67Zn in hexagonal close-packed Zn metal has been observed at 4.2 K by pulsed NMR with three different frequencies. The spin echo profile showed a well resolved powder pattern due to electric quadrupole interaction. The quadrupole coupling constant was determined to be e2 q Q/h = 12.0 (4) MHz. The spin-spin and spin-lattice-relaxation times were measured to be T2 = 58 ± 2 ms and T1 = 0.45 ± 0.2 s, respectively. The isotropic Knight shift is found to have the value Kiso = 0.1 ± 0.05%.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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