Investigation of the Zero-Field Splitting of d8 Ions in Pseudo-tetragonal Ni(II) Compounds-Reference-Cited by-同舟云学术

Investigation of the Zero-Field Splitting of d8 Ions in Pseudo-tetragonal Ni(II) Compounds

Published:1994-11-01 Issue:11 Volume:49 Page:1013-1015
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Chen Jia-Jun¹,Du Mao-Lu²,Li Zhao-Ming²

Affiliation:

1. Department of Physics, Sichuan Teachers’ College, Nan Chong 637002, P.R. China

2. CCAST (World Laboratory), P.O. Box 8730, Beijing 100080, P.R. China and Institute of Solid State Physics, Sichuan Normal University, Chengdu 610066, P.R. China

Abstract

Abstract This paper presents a cluster approach to the zero-field splitting (ZFS) of the ground state 3A2(F) of d8 ions with tetragonal symmetry, in which not only the spin-orbit coupling of the central transition-metal-ion but also that of ligands contributes. For some pseudo-tetragonal Ni(II) com pounds the calculated values of the ZFS parameter follow the order Cl-> Br-> I-. This agrees with the experimental finding, while the pure crystal field approach considering only the coupling of central metal ion yields the opposite trend.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1994-1102/pdf

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Electrophilic Double-Sandwiches Formed by Interaction of [Cp2Fe] and [Cp2Ni] with the Tridentate Lewis Acid [(o-C6F4Hg)3];Angewandte Chemie International Edition;2004-10-13

2. Electrophilic Double-Sandwiches Formed by Interaction of [Cp2Fe] and [Cp2Ni] with the Tridentate Lewis Acid [(o-C6F4Hg)3];Angewandte Chemie;2004-10-13

3. Theoretical Investigations of theg-Factors and Hyperfine Structure Constants for a Tetragonal Co2+ Centre in NH4Cl Crystal;physica status solidi (b);2000-08

4. g factor of Cu2+ with 2A1g ground state;Physica B: Condensed Matter;1997-04

5. Investigation of the zero-field splitting and g-values of d8 ions in trigonal compounds CsMgX3:Ni2+ (X = Cl, Br, I);Physica B: Condensed Matter;1996-11