Reanalysis of the Nuclear Quadrupole Coupling in the Rotational Spectrum of N-Methylpyrrole

Author:

Huber S. R.1,Bauder A.1

Affiliation:

1. Laboratorium für Physikalische Chemie, Eidgenössische Technische Hochschule, ETH-Zentrum, CH -8092 Zürich, Switzerland

Abstract

Abstract The rotational spectrum of N-methylpyrrole has been measured with pulsed nozzle Fourier transform microwave spectrometers between 6 and 38 GHz. The quadrupole hyperfine structure due to 14N has been reanalyzed in the A (m = 0) state o f the methyl internal rotation. Improved rotational constants, centrifugal distortion constants, and quadrupole coupling constants have been simultaneously determined from the measured transition frequencies in an iterative least-squares fit.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. The Calculation of Electric Field Gradients byab initioMethods, and Their Relationship to Experimental Nuclear Quadrupole Coupling Constants;Encyclopedia of Computational Chemistry;2005-07-15

2. Internal rotation of the methyl group in the S0 and S1 (3s Rydberg) electronic states of N-methylpyrrole;Chemical Physics Letters;2002-02

3. An appreciation of Alfred Bauder;Journal of Molecular Structure;2001-12

4. 2.7.4.3 References for 2.7.4.2;Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules

5. No. 144 C3H5NO2 - No. 229 ClFH2S;Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules

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