Systematic Investigation of MF3 Crystalline Compounds (M = Al, Cr, Fe, Ga, In, Sc, Ti, and V) and Fe1-xMxF3 Mixed Series (M = Ga, Cr, V)

Author:

Blank H.-R.1,Frank M.1,Geiger M.1,Greneche J.-M.2,Ismaier M.1,Kaltenhäuser M.1,Kapp R.1,Kreische W.1,Leblanc M.3,Lossen U.1,Zapf B.1

Affiliation:

1. Physikalisches Institut der Universität Erlangen-Nürnberg, Erwin-Rommel-Str. 1, 91058 Erlangen, Germany

2. URA CNRS 807, Faculte des Sciences, Universite du Maine, 72017 Le Mans, BP 535, Cedex, France

3. URA CNRS 449, Faculte des Sciences, Universite du Maine, 72017 Le Mans, BP 535, Cedex, France

Abstract

Abstract The electric field gradient at the fluorine site of several crystalline trifluorides was measured by means of the time differential perturbed angular distribution method. The hyperfine data (vQ and η) are systematically analyzed by taking into account the structural parameters of the crystals; they are also compared to the results obtained by point charge calculations.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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