Affiliation:
1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim an der Ruhr
Abstract
Regioselective reduction of a homologous series of O-n-hexyl to O-n-hexadecyl 2,3:5,6-bis-O-ethylboranediyl-β-D-mannofuranosides, la-k is achieved with ethyldiboranes(6) in the presence of 9-methanesulfonyloxy-9-borabicyclo[3.3.1] nonane [MSBBN]. After deboronation the mesogenic 1-O-n-alkyl-D-mannitols 2a-k are obtained, the liquid crystal ranges and solid state transitions of which are determined by D.S.C.
Cited by
17 articles.
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