Affiliation:
1. Universität Dortmund, Fachbereich Chemie, Anorganische Chemie, Postfach 500500, D-4600 Dortmund 50
Abstract
The preparations and characterizations of compounds SCl2F+MF6~ (M = As, Sb) are reported. They are yellowish hydrolysable solids, with a strong tendency towards symmetrization in solution. The mass spectra data indicate the formation of SCl2F2 on thermolysis. The series of SClnF3-n
+-cations (n = 0—3) is now complete, and a comprehensive discussion of the spectroscopic data is given.
Cited by
7 articles.
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1. Syntheses of [F5TeNH3][AsF6], [F5TeN(H)Xe][AsF6], and F5TeNF2 and Characterization by Multi-NMR and Raman Spectroscopy and by Electronic Structure Calculations: The X-ray Crystal Structures of α- and β-F5TeNH2, [F5TeNH3][AsF6], and [F5TeN(H)Xe][AsF6];Inorganic Chemistry;2006-02-07
2. The reaction of XeF+MF6? (M = As, Sb) with sulfuranes; preparation of CF3(O)F2+SbF6? and (CF3)2SOXeF+SbF6?;Zeitschrift f�r anorganische und allgemeine Chemie;1992-06
3. Synthese von (C6F5)2SF+MF6? (M ? As, Sb) und Kristallstruktur von (C6F5)2SF+SbF6? [1];Zeitschrift f�r anorganische und allgemeine Chemie;1992-05
4. Raman spectra of some complexes containing methyldihalo- and dimethylhalo-sulphonium cations: Isomerism in the dimethyl sulphide-bromine complex;Journal of Raman Spectroscopy;1991-05
5. Darstellung von Cyanhalogenmethyl- und Dicyanhalogensulfoniumsalzen CH3(CN)SHal+MF6? und (CN)2 SHal+MF6? (Hal = F, Cl, Br, I; M = As, Sb) sowie von Methylthionitrillium- und (?-Thio)bisnitriliumhexafluorometallaten CH3SCNX+MF6? und S(CNH)22+ (MF6?)2 (X = H, D);Zeitschrift f�r anorganische und allgemeine Chemie;1991-04