Reaktion des Oxovanadium(V)-trichlorids mit tert-Butylamin und silylierten Derivaten/Reaction of Oxovanadium (V) Trichloride with tert-Butylamine and Silylated Derivatives

Abstract

Abstract A m ino and Im inovanadium (V) C om pounds, Preparation, 5IV NM R Spectra The reaction o f V O C l3 with rm -butylam ine and silylated derivatives has been studied. 0 = V C 1 2[N'C4H 9(R)] (R = SiM e3, SiM e2NH'C4H 9), 0 = V (0 S i M e 3)2Cl and binuclear vanadium (V) com plexes with bridging oxo and nitrogen ligands have been prepared; their spec­ troscopic data ('H N M R ,51V N M R , IR) are reported. A simple route for preparing'C4H 9N =V C 13 and ['C4H 9N = V (0)C 1]" is described including com plex formation with pyridine and chloride ions.