Syntheses and crystal structures of three bis(triorganotin) benzenedicarboxylates

Author:

Liu Jin,Liu Min,Wang Shiqing,Li Yuxiao,Liu Mingzhu,Wang Yue,Tian Laijin,Liu Xicheng

Abstract

Abstract Three bis(triorganotin) benzenedicarboxylates, 1,n-C6H4(COOSnR3)2 (n, R=3, C6H5C(CH3)2CH2, 1; 4, C6H5C(CH3)2CH2, 2; 4, C6H11-c, 3), were synthesized by the reaction of 1,3 or 1,4-benzenedicarboxylic acid with triorganotin chlorides in the solution of CH3ONa-CH3OH and characterized by means of elemental analysis, Fourier-transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) (1H, 13C, and 119Sn) spectra, and X-ray single-crystal diffraction. Compounds 1–3 are all di-nuclear tin complexes in which the carboxylate is monodentate and each tin atom possesses a distorted SnC3O tetrahedral geometry.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry

Reference48 articles.

1. Self-assembled triorganotin(IV) moieties with 1,3,5-benzenetricarboxylic acid: syntheses and crystal structures of monomeric, helical, and network triorganotin(IV) complexes;Eur. J. Inorg. Chem.,2005

2. Synthesis, characterization, and cytotoxic activity of triphenyltin complexes of N-(5-bromosalicylidene)-α-amino acids;Main Group Met. Chem.,2017

3. Antiproliferative and anti-tumor activity of organotin compounds;Coord. Chem. Rev.,2009

4. A short history of SHELX;Acta Crystallogr.,2008

5. Antiproliferative and anti-tumor activity of organotin compounds;Coord. Chem. Rev.,2009

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3