An efficient and convenient aldol addition of acyldiazomethane with aldehydes promoted by MgI2 etherate-Reference-Cited by-同舟云学术

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An efficient and convenient aldol addition of acyldiazomethane with aldehydes promoted by MgI2 etherate

Published:2017-01-01 Issue:3-4 Volume:40 Page:
ISSN:2191-0219
Container-title:Main Group Metal Chemistry
language:
Short-container-title:

Author:

Xie Xiaoqiang,Qi Weipeng,Sun Xinzhe,Zhang Xingxian

Abstract

AbstractThe aldol addition of acyldiazomethane with aromatic aldehydes, vinyl aldehyde and aliphatic aldehydes was carried out efficiently in the presence of MgI

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/mgmc-2017-0006/pdf

Reference58 articles.

1. Zinc derivative of ethyl diazoacetate in the synthesis of α-diazo β-hydroxy esters;Synthesis,1998

2. The first catalytic enantioselective aldol-type reaction of ethyl diazoacetate to ketones;Adv. Synth. Catal.,2009

3. Highly enantioselective synthesis of α-diazo-β-hydroxy esters using a bifunctional titanium complex;Synlett,2009a

4. Preparation of α-diazo-β-hydroxy esters using tert-BuOK in water and PEG;Catal. Commun.,2005

5. Catalysis in water. Aldol-type reaction of aldehydes and imines with ethyl diazoacetate catalyzed by highly basic magnesium/lanthanum mixed oxide;Adv. Synth. Catal.,2007a

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