Affiliation:
1. Key Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University, Qufu 273165, China
2. Department of Resources and Environmental, Shandong Water Polytechnic, Rizhao 276826, China
Abstract
Abstract
Two [2-((L)-menthoxycarbonyl)ethyl]diphenyltin halides, (L)-MenOCOCH2CH2SnXPh2 (X=Cl, 1; I, 2), have been synthesized and characterized by means of elemental analysis, FT-IR, NMR (1H, 13C, and 119Sn) spectroscopy, and X-ray single crystal diffraction. The tin atoms in 1 and 2 are both five-coordinated and possess the [C3SnOX] (X=Cl and I) trigonal bipyramidal environment with the trigonal plane defined by the three carbon atoms and the axial positions occupied by the halogen atom and internal carbonyl oxygen. There is a five-membered chelate ring in 1 and 2 with the Sn-O distance being 2.4781(16) and 2.512(2) Å, respectively.
Subject
Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry
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