Crystal structure of bis[hydrido-hexaphenylcarbodiphosphoran][tetra-trifluoromethyl-(μ-diiodo)-diplatinat]

Author:

Petz Wolfgang1ORCID,Neumüller Bernhard1

Affiliation:

1. Fachbereich Chemie, Philipps Universität Marburg , Hans-Meerwein-Strasse, D-35032 Marburg , Germany

Abstract

Abstract C86H78F12I2O2P4Pt2, triclinic, P 1 $P\overline{1}$ (no. 2), a = 11.520(1) Å, b = 12.196(1) Å, c = 15.382(2) Å, α = 73.20(1)°, β = 75.18(1)°, γ = 86.81(1)°, V = 2000.1(4) Å3, Z = 1, R gt (F) = 0.0631, wR ref (F 2) = 0.1759, T = 193(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference11 articles.

1. STOE & Cie. X-AREA (version 1.18) and X-RED (version 1.04); Stoe & Cie: Darmstadt, Germany, 2002.

2. Altomare, A., Cascarano, G., Giacovazzo, C., Guagliardi, A., Burla, M. C., Polidori, G., Camalli, M. SIR-92; Altomar: Rome, 1992.

3. Sheldrick, G. M. SHELXL-2016/6, Program for the Refinement of Crystal Structures; University of Goettingen: Goettingen, Germany, 2016.

4. Petz, W., Wenck, K., Neumüller, B. On the reaction of C(PPh3)2 with [Co2(CO)8]: formation and structure of an unusual tetranuclear cluster. Z. Naturforsch. 2007, 62b, 413–418; https://doi.org/10.1515/znb-2007-0315.

5. Petz, W., Öxler, F., Ronge, R., Neumüller, B. An unusual product from the reaction of C(PPh3)2 with [Mn2(CO)10]: formation and crystal structure of [Mn(OPPh3)2{O2CC(PPh3)2}2][Mn(CO)5]2. Z. Anorg. Allg. Chem. 2008, 634, 1415–1420.https://doi.org/10.1002/zaac.200800119.

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