The crystal structure of 6,6′-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2-chloro-4-methyl phenolate-κ 4 N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV), C27H27Cl2N3O6Ti-Reference-Cited by-同舟云学术

The crystal structure of 6,6′-(((2-(dimethylamino)ethyl)azanediyl)bis(methylene))bis(2-chloro-4-methyl phenolate-κ ⁴ N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV), C₂₇H₂₇Cl₂N₃O₆Ti

Published:2023-07-26 Issue:5 Volume:238 Page:817-819
ISSN:1433-7266
Container-title:Zeitschrift für Kristallographie - New Crystal Structures
language:en
Short-container-title:

Author:

Yang Mingjun¹,Wang Canghai¹^ORCID

Affiliation:

1. College of Life Science and Engineering , Lanzhou University of Technology , Lanzhou 730050 , Gansu , P.R. China

Abstract

Abstract C27H27Cl2N3O6Ti, monoclinic, P21/c (no. 14), a = 11.609(4) Å, b = 21.476(7) Å, c = 13.504(4) Å, β = 109.881(9)°, V = 3166.2(18) Å3, Z = 4, Rgt (F) = 0.0623, wRref (F 2) = 0.1945, T = 100(1) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/ncrs-2023-0168/pdf

Reference11 articles.

1. Bruker. SMART and SAINT for Windows NT Software Reference Manuals, (version 5.0); Bruker Analytical X-Ray Systems: Madison, WI, 1997.

2. Sheldrick, G. A short history of SHELX. Acta Crystallogr. A 2008, 64, 112–122; https://doi.org/10.1107/s0108767307043930.

3. Peri, D., Manna, C. M., Shavit, M., Tshuva, E. Y. Ti(IV) Complexes of branched diamine bis(phenolato) ligands: hydrolysis and cytotoxicity. Eur. J. Inorg. Chem. 2011, 2011, 4896–4900; https://doi.org/10.1002/ejic.201100725.

4. Zhao, T., Wang, P., Liu, N., Li, S., Yang, M., Yang, Z. Facile synthesis of [ONON] type titanium(IV) bis-chelated complexes in alcoholic solvents and evaluation of anti-tumor activity. J. Inorg. Biochem. 2022, 235, 111925; https://doi.org/10.1016/j.jinorgbio.2022.111925.

5. Köpf, H., Köpf-Maier, P. Titanocene dichloride-the first metallocene with cancerostatic activity. Angew. Chem. Int. Ed. Engl. 1979, 18, 477–478; https://doi.org/10.1002/anie.197904771.