Crystal structure of bis(μ 3-diphenylphosphinato)-tetrakis(μ 2-diphenylphosphinato)-bis(diphenylphosphinato)-bis(μ 2-hydroxo)dicopper(II)-ditin(IV), C104H100O18P8Cu2Sn2

Author:

Xiaolin Sun1ORCID,Yuhua Guo2,Youzhu Yu2ORCID

Affiliation:

1. College of Chemistry and Material Science, Shanxi Normal University , Taiyuan , 030006 Shanxi , P. R. China

2. School of Chemical and Environmental Engineering, Anyang Institute of Technology , Anyang , 455000 Henan , P. R. China

Abstract

Abstract C104H100O18P8Cu2Sn2, triclinic, P 1 $P\overline{1}$ (no. 2), a = 13.8254(6) Å, b = 14.1283(6) Å, c = 15.1940(7) Å, α = 112.571(1)°, β = 104.707(1)°, γ = 104.433(1)°, V = 2442.87(19) Å3, Z = 1, R gt (F) = 0.0256, wR ref (F 2) = 0.0955, T = 296(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference13 articles.

1. Bruker. APEX2; Bruker AXS Inc.: Madison, Wisconsin, USA, 2005.

2. Bruker. SAINT-Plus; Bruker AXS Inc.: Madison, Wisconsin, USA, 2001.

3. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.

4. Brandenburg, K. DIAMOND. Visual Crystal Structure Information System. Version 3.2i; Crystal Impact: Bonn, Germany, 2012.

5. Zhu, Y., Zhang, L., Zhang, J. Assembly of high-nuclearity Sn26, Sn34-oxo clusters: solvent strategy and inorganic Sn incorporation. Chem. Sci. 2019, 10, 9125–9129; https://doi.org/10.1039/c9sc02503k.

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