Crystal structure of (μ2-1,1′-bis(diphenylphosphino)ferrocene-P,P′)-bis[(Z)-O-isopropyl N-(4-chlorophenyl)thiocarbamato-S]-di-gold(I) acetonitrile di-solvate, C54H50Au2Cl2FeN2O2P2S2⋅2(C2H3N)

Author:

Yeo Chien Ing1,Tiekink Edward R.T.1

Affiliation:

1. Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia

Abstract

AbstractC58H56Au2Cl2FeN4O2P2S2, triclinic, P1̄ (no. 2), a = 8.5422(3) Å, b = 13.2143(4) Å, c = 14.0226(4)) Å, α = 65.764(3)°, β = 78.311(2)°, γ = 80.090(3)°, V = 1406.39(8) Å3, Z = 1, Rgt(F) = 0.0213, wRref(F2) = 0.0477, T = 100 K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference20 articles.

1. Principles of crystal packing in O-isopropyl-N-aryl-thiocarbamides: iPrOC(=S)N(H)C6H4-4-Y: Y = H, Cl, and Me;CrystEngComm,2007

2. A short history of SHELX;Acta Crystallogr,2008

3. [μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′]bis{[(Z)-O-isopropyl-N-(4-methylphenyl)thiocarbamato-κS]gold(I)};Acta Crystallogr,2009

4. Utilizing Hirshfeld surface calculations, non-covalent interaction (NCI) plots and the calculation of interaction energies in the analysis of molecular packing;Acta Crystallogr,2019

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