The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ4 N 4-naphthalocyanido-κ4 N 4-neodymium(IV) - chloroform (1/6) C114H90N12Cl18Nd-Reference-Cited by-同舟云学术

The crystal structure of 5,10,15,20-tetrakis(4-(tert-butyl)phenyl)porphyrin-21,23-diido-κ⁴ N ⁴-naphthalocyanido-κ⁴ N ⁴-neodymium(IV) - chloroform (1/6) C₁₁₄H₉₀N₁₂Cl₁₈Nd

Published:2022-11-01 Issue:1 Volume:238 Page:9-12
ISSN:1433-7266
Container-title:Zeitschrift für Kristallographie - New Crystal Structures
language:en
Short-container-title:

Author:

Liguo Yang¹^ORCID,Xin Wang¹,Jiaqi Fu¹,Xinyu Ji¹

Affiliation:

1. College of Chemistry and Environmental Engineering , Anyang Institute of Technology , Anyang 455000 , Henan , P.R. China

Abstract

Abstract C114H90N12Cl18Nd, triclinic, P 1 ‾

$P\overline{1}$

(no. 2), a = 17.3389(7) Å, b = 18.7671(5) Å, c = 19.1454(8) Å, α = 79.600(3)°, β = 68.752(4)°, γ = 68.572(3)°, V = 5396.7(4) Å3, Z = 2, R gt (F) = 0.0722, wR ref (F 2) = 0.1979, T = 298 K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/ncrs-2022-0405/pdf

Reference10 articles.

1. SMART and SAINT for Windows NT Software Reference Manuals, Version 5.0; Bruker Analytical X–Ray Systems: Madison, WI, 1997.

2. Sheldrick, G. M. SADABS, A Software for Empirical Absorption Correction; University of Göttingen: Göttingen, Germany, 1997.

3. SHELXL Reference Manual, Version 5.1; Bruker Analytical X–Ray Systems: Madison, WI, 1997.

4. Bian, Y., Wang, R., Jiang, J., Lee, C. H., Wang, J., Ng, D. K. P. Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes. Chem. Commun. 2003, 10, 1194–1195; https://doi.org/10.1039/b301139a.

5. Wang, H., Kang, W., Bian, Y., Jiang, J., Kobayashi, N. Mixed (phthalocyaninato)(porphyrinato) heterometal complexes with sandwich quadruple-decker molecular structure. Chem. Commun. 2011, 47, 6879–6881; https://doi.org/10.1039/c1cc11190f.