Crystal structure of (μ2-1,1′-bis(diphenylphosphino)hexane-κ2P,P′)-bis[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-κS]digold(I), C46H46Au2F2N2O2P2S2

Author:

Yeo Chien Ing1,Tiekink Edward R.T.1

Affiliation:

1. Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia

Abstract

AbstractC46H46Au2F2N2O2P2S2, triclinic, P1̄ (no. 2), a = 8.2496(3) Å, b = 11.4366(4) Å, c = 12.9504(4) Å, α = 109.171(3)°, β = 92.496(3)°, γ = 100.208(3)°, V = 1128.98(7) Å3, Z = 1, Rgt(F) = 0.0246, wRref(F2) = 0.0560, T = 100(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference20 articles.

1. A conformational polymorph of Ph3PAu[SC(OEt)=NPh] featuring an intramolecular Au⋯π interaction;Z. Kristallogr. CM,2016

2. [(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS]-(triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study;Acta Crystallogr,2020

3. Pathogenic Gram-positive bacteria are highly sensitive to triphenylphosphanegold(O-alkylthiocarbamates), Ph3PAu[SC(OR)=N(p-tolyl)] (R = Me, Et and iPr);Gold Bull,2013

4. A conformational polymorph of Ph3PAu[SC(OEt)=NPh] featuring an intramolecular Au⋯π interaction;Z. Kristallogr. CM,2016

5. A short history of SHELX;Acta Crystallogr,2008

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