Indolyl- und Pyrrolylsilane – Synthese und Kristallstruktur / Indolyl- and Pyrrolylsilanes – Syntheses and Crystal Structures

Abstract

Lithium indolide and lithium pyrrolide react with fluoro- and chlorosilanes with formation of mono- and bis(indol-1-yl)- and -(pyrrol-1-yl)silanes, tris- and tetrakis(pyrrol-1-yl)silanes as well as of silanes substituted with different heteroaromatic systems. The crystal structures of the lithium indolide and the tetrakis(pyrrol-1-yl)silane have been determined and are discussed.