Affiliation:
1. Institut für Anorganische Chemie der Christian-Albrechts-Universität zu Kiel, Olshausenstraße 40, D-24098 Kiel
Abstract
Single crystals of Ag0.5Cu3V0,5Mo2,5O12 have been prepared by crystallization from melts and investigated by X -ray methods. They crystallize with triclinic symmetry, space group Ci
1 -P 1̄ , a = 6.797(6), b = 8.575(6), c = 9.897(7) Å, α = 103.47(6), β = 103.69(6), γ = 101.48(6)° and Z = 4. The crystal structure is characterized by chains of edge-sharing CuO6 octahedra and CuO5 pyramids. Special features of this com pound are the square planar surrounding of Ag+ by O2− and a statistical distribution of molybdenum and vanadium at one point position.
Cited by
6 articles.
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1. Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia;Mineralogical Magazine;2013-02
2. ChemInform Abstract: A Silver Copper Oxovanadate-Oxomolybdate with Silver in Square Planar Coordination: Ag0.5Cu3V0.5Mo2.5O12.;ChemInform;2010-08-17
3. Square planar silver(I) complexes: A rare but increasingly observed stereochemistry for silver(I);Coordination Chemistry Reviews;2008-07
4. Zur Kristallchemie der Oxoargentate und Silberoxometallate;Zeitschrift f�r anorganische und allgemeine Chemie;2004-11
5. Phase formation in the systems Ag2MoO4–MO–MoO3 (M=Ca, Sr, Ba, Pb, Cd, Ni, Co, Mn) and crystal structures of Ag2M2(MoO4)3 (M=Co, Mn);Journal of Solid State Chemistry;2004-06