Synthese und Struktur von 2-Imino-1,3-dimethylimidazolin / Synthesis and Structure of 2-Imino-1,3-dimethylimidazoline-Reference-Cited by-同舟云学术

Synthese und Struktur von 2-Imino-1,3-dimethylimidazolin / Synthesis and Structure of 2-Imino-1,3-dimethylimidazoline

Published:1995-12-01 Issue:12 Volume:50 Page:1779-1784
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Kuhn Norbert¹,Fawzi Riad¹,Steimann Manfred¹,Wiethoff Jörg¹,Bläser Dieter²,Boese Roland²

Affiliation:

1. Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen

2. Institut für Anorganische Chemie der Universität-Gesamthochschule Essen, Universitätsstraße 3 -5 , D-45117 Essen

Abstract

Deprotonation of the 2-amino- 1,3-dimethylimidazolium salt 5 (obtained through methylation of 2-amino-l-methylimidazole (4)) by KH gives 2-imino-1,3-dimethylimidazoline 6. The trimethylsilylimino compound 14 is formed on the reaction of 6 with chlorotrimethylsilane in the ratio 2:1. Further reaction with chlorotrimethylsilane gives the silylated aminoimidazolium salt 15. The X-ray structures of 5 and 6 are reported.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1995-1202/pdf

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