Preparation and Characterization of (C6H5CH2CH2NH3)4BiI7 · H2O, (C6H5CH2CH2NH3)3BiBr6 and (C6H5CH2CH2NH3)3BiCl6-Reference-Cited by-同舟云学术

Preparation and Characterization of (C6H5CH2CH2NH3)4BiI7 · H2O, (C6H5CH2CH2NH3)3BiBr6 and (C6H5CH2CH2NH3)3BiCl6

Published:1995-10-01 Issue:10 Volume:50 Page:1566-1569
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Papavassiliou G. C.¹²,Koutselas I. B.¹,Terzis A.³,Raptopoulou C. P.¹

Affiliation:

1. Theoretical and Physical Chemistry Institute. National Hellenic Research Foundation, 48, Vassileos Constantinou Ave., Athens 11635. Greece

2. Prof. G. C. Papavassiliou

3. Institute of Materials Science. NCCR, Demokritos, Aghia Paraskevi. Athens 153-10, Greece

Abstract

The title compounds were prepared and characterized analytically, structurally, and spectroscopically. They contain isolated BiX6 (X = I. Br, Cl) anions. Their optical absorption spectra show excitonic bands in the UV-visible spectral region. These bands occur at higher energies than the corresponding bands of R3M2X9 (R = MemNH4-m; m = 1,2, 3, 4).

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1995-1023/pdf

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