Crystal structure of bis(ethanaminium) poly[bis(hexaselenido-κ2Se1,Se6)palladate(II)], C4H16N2PdSe12

Author:

Kim Kang-Woo1,Wang Di1

Affiliation:

1. 1Department of Chemistry and Research Institute for Natural Sciences, Incheon National University, Incheon 22012, Korea

Abstract

AbstractC4H16N2PdSe12, monoclinic, C2/c (No. 15), a = 16.8578(5) Å, b = 7.6646(2) Å, c = 16.7440(5) Å, β = 94.7894(15)°, V = 2155.91(11) Å3, Z = 4, Rgt(F) = 0.0351, wRref(F2) = 0.0722, T = 173 K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference16 articles.

1. Crystal structure of bis(N,N,N-triethylammonium) bis(tetraselenido-κ2Se1,Se4)palladate(II), C12H32N2PdSe8;Z. Kristallogr. NCS,2015

2. Crystal structure of bis(N,N,N-triethylammonium) bis(tetraselenido-κ2Se1,Se4)palladate(II), C12H32N2PdSe8;Z. Kristallogr. NCS,2015

3. Powerful templating effect in Rb/Pd/Sexpromoted by crown ether-like [Rb(Se8)]+ coordination. Formation of Rb2[Pd(Se4)2]·Se8: A layered Pd polyselenide with "Encapsulated" eight-membered selenium rings;J. Am. Chem. Soc.,1999

4. Counterion effects in Pd polyselenides: evolution from molecular to three-dimensional framework structures;J. Am. Chem. Soc.,1998

5. Hydrothermal synthesis of K2PdSe10. coexistence of two large interpenetrating three-dimensional frameworks of [Pd(Se4)2]2− and [Pd(Se6)2]2−;J. Am. Chem. Soc.,1992

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