Crystal structure of monocarbonyl(N-nitroso-N-oxido-phenylamine-κ2O,O′)(triphenylarsine-κAs)rhodium(I), C25H20AsN2O3Rh

Author:

Drost Ruben M.1,Koen Renier1,Roodt Andreas1,Venter Johan A.1

Affiliation:

1. 1Department of Chemistry, University of the Free State, Nelson Mandela Ave, Bloemfontein, South Africa

Abstract

AbstractC25H20AsN2O3Rh, triclinic, P-1 (no. 1), a = 9.2781(15) Å, b = 10.1405(15) Å, c = 13.303(2) Å, α = 99.789(5)°, β = 107.971(5)°, γ = 94.089(5)°, V = 1162.9(3) Å3, Z = 2, Rgt(F) = 0.0578, wRref(F2) = 0.1833, T = 100(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference30 articles.

1. Structure of penta-coordinated b-carbonyl-cd-(N-hydroxy-N-nitrosobenzenaminato-O,O′)-ae-bis-(triphenylphosphine)rhodium(I);Acta Crystallogr.,1990

2. Synthesis and characterization of rhodium(I) 2-methylcupferrate complexes and their kinetic behaviour in iodomethane oxidative addition;J. Organomet. Chem.,2013

3. Di-μ-iodido-bis[acet-yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo-[2.2.2]octane)(N-nitroso-N-oxidoaniline-O,O′)rhodium(III)];Acta Crystallogr.,2009

4. WinGX suite for small-molecule single-crystal crystallography;J. Appl. Crystallogr.,1999

5. Structure of penta-coordinated b-carbonyl-cd-(N-hydroxy-N-nitrosobenzenaminato-O,O′)-ae-bis-(triphenylphosphine)rhodium(I);Acta Crystallogr.,1990

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