Crystal structure of a new polymorph of bis[μ-1,3-bis(diphenylphosphino)propane-κ2P:P′-disilver(I)] bis(tetrafluoroborate), [Ag(dppp)]2(BF4)2, C54H52Ag2B2F8P4

Author:

Kuang Xiao-Nan1,Lin Sen1,Li Si-Fan1,Li Yue1,Xin Xiu-Lan2,Jin Qiong-Hua1

Affiliation:

1. Department of Chemistry, Capital Normal University, Beijing 100048, P.R.China

2. School of Food and Chemical Engineering, Beijing Industry and Business University, Beijing 100048, P.R. China

Abstract

AbstractC54H52Ag2B2F8P4, triclinic, Pa = 11.4869(4) Å, b = 12.9118(5) Å, c = 19.6858(6) Å, α = 100.8240(10)°, β = 102.185(2)°, γ = 110.470(3)°, V = 2562.31(15) Å3, Z = 2, Rgt(F) = 0.0263, wRref(F2) = 0.0666, T = 293(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference14 articles.

1. Bis[μ-1,3-bis(diphenylphosphino)propane]-disilver(I)bis(tetrafluoroborate);Acta Crystallogr,2003

2. Polymers and rings in gold(I) diphosphine complexes: linking gold rings through aurophilic interactions;Chem. Commun,2001

3. Ring, polymer and net work structures in silver(I) complexes with dipyridyl and diphosphine ligands;Chem. Commun,2001

4. Polymers and rings in gold(I) diphosphine complexes: linking gold rings through aurophilic interactions;Chem. Commun,2001

5. Crystal structure refinement with SHELXL;Acta Crystallogr,2015

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