Vibration-Rotation Interaction in the Microwave Spectrum of KOH

Author:

Kuijpers P.1,Törring T.12,Dymanus A.1

Affiliation:

1. Fysisch Laboratorium, Katholieke Universiteit Nijmegen, The Netherlands

2. Permanent address: Institut für Molekülphysik, Freie Universität Berlin.

Abstract

Abstract The fine structure of the microwave transition J=6←5 of 39KOH and 41KOH has been studied. The analysis results in improved vibration-rotation interaction constants, a1 , a2, y22, yll and ql. It is shown that coupling between the bending and stretching vibrational modes contributes to the observed frequencies.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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